Can green solvents provide the key to sustainable manufacturing of hollow fiber membranes?

Researchers of the research department Surfaces of Porous Membrane Filters at the IOM have investigated an alternative to conventional, environmentally harmful solvents for membrane production: N,N-dimethyl lactamide (Agnique® AMD 3L), a solvent that is more environmentally friendly and can be used to produce PES hollow fiber membranes. The core findings are as follows: Using a Design of Experiments (DoE) approach, the team successfully identified the optimal conditions to produce macrovoid-free, sponge-like membrane structures, which are known for their superior mechanical strength and uniform pore distribution. Crucially, the team found that high-molecular-weight PVP (360 kDa) was essential for forming stable sponge-like morphologies.
In summary: Environmentally friendly solvents like N,N-dimethyl lactamide has the potential to yield two key benefits: the production of high-performance membranes and the reduction of the lower ecological footprint. This dual benefit is a significant advancement in the field of sustainable separation technologies, offering a mutually beneficial solution to both environmental and economic concerns.
This study establishes a solid foundation for future solvent replacement strategies and greener membrane manufacturing processes.

The results were recently published:

Konrad H. Leopold, Daniel Breite, Martin Schmidt, Andrea Prager, Marco Went, Mathias Kühnert, Dirk Enke, Agnes Schulze
Design of sponge-like PES hollow fiber membranes using the environmentally friendly solvent N,N-dimethyl lactamide
Separation and Purification Technology, Vol. 365, 132625 (2025)
https://doi.org/10.1016/j.seppur.2025.132625